[Research on the Quality Control of Routine Reusable Pipeline and Disposable Pipeline of Ventilator].

Objective: To explore the effect of routine reusable pipeline and disposable pipeline on ventilator quality control results. Methods: 17 ventilators were randomly selected to conduct quality control using routine reusable pipeline and disposable pipeline respectively. Quality control data were recorded and then paired t-test method was used to analyze whether the difference between the two pipelines was significant or not. Results: There were no significant differences in respiratory rate, tidal volume and end airway pressure between the two types of pipes ( P＞0.05). The airway peak pressure of routine reusable pipeline was significantly higher than disposable pipeline ( P＜0.05), but the difference was very small, only about 0.2 mbar which would not affect the conclusion of quality control. Conclusion: Quality control of ventilator is not affected by routine reusable pipeline and disposable pipeline, which can be replaced by each other.

P/N-heteroleptic Cu(I)-photosensitizer-catalyzed domino radical relay annulation of 1,6-enynes with aryldiazonium salts.

A visible-light driven photocatalytic construction of benzo[b]fluorenones from 1,6-enynes and aryldiazonium salts has been achieved via a P/N-heteroleptic Cu(I)-photosensitizer-catalyzed domino radical relay annulation process. Preliminary mechanistic studies revealed that the aryl radicals in situ generated from aryldiazonium salts with the excited state of the Cu(I)-photosensitizer played a dual role of a radical initiator and a radical terminator in the concise construction of the highly fused benzo[b]fluorenone scaffold.

Approach to Access Benzo[j]phenanthridinones from 1,7-Enynes and Aryldiazonium Salts via a Domino Radical Relay Process Enabled by a P/N-Heteroleptic Cu(I)-Photosensitizer.

A mild approach for the synthesis of benzo[j]phenanthridin-6(5H)-one derivatives from 1,7-enynes and aryldiazonium salts has been successfully developed involving a domino radical relay process enabled by a heteroleptic Cu(I)-photosensitizer under visible-light-driven photocatalytic conditions. Mechanistic studies disclosed that the oxidative quenching of the excited state of PS 4 with aryldiazonium salts via an SET process generated aryl radicals, which could play a radical initiator-terminator dual role within the whole radical relay process, namely, at the initial step acting as a radical donor to trigger the radical addition to the olefin moieties of 1,7-enynes while at the final stage serving as a radical acceptor to complete the cyclization.

P/N-Heteroleptic Cu(I)-Photosensitizer-Catalyzed [3 + 2] Regiospecific Annulation of Aminocyclopropanes and Functionalized Alkynes.

We report here a regiospecific [3 + 2] annulation between aminocyclopropanes and various functionalized alkynes enabled by a P/N-heteroleptic Cu(I) photosensitizer under photoredox catalysis conditions. Thus, a divergent construction of 3-aminocyclopentene derivatives including methylsulfonyl-, arylsulfonyl-, chloro-, ester-, and trifluoromethyl-functionalized aminocyclopentenes could be achieved with advantages of high regioselectivity, broad substrate compatibility, and mild and environmentally benign reaction conditions.

Embroidering a Filmsy Photorechargeable Energy Fabric with Wide Weather Adaptability.

To provide a light and breathable self-charging wearable power source adaptable for various weather conditions and body movements, couching embroidery has been proposed as an industrially scalable electrode-to-device assembling strategy, rather than a decorative textile pattern making process. Various types of cable electrodes and device units with a large size and shape difference were directly and reliably assembled on a light and soft tulle to form either photovoltaic or battery devices, which can be further integrated following any irregular pattern and any electrical connection design. Under sunlight, a transparent tulle as a glove or scarf can be charged up at a power of 10 W/m2, and then maintain stable power output in the dark for various weather and body moving conditions, including bending, twisting, hand-stretching, wind blowing, and water washing. Our approaches not only simplified the fabrication of integrated fabric-type energy devices but also improved the structural and functional design flexibility of a portable electronic power source, especially for summer wearing applications.

Self-Powered All-in-One Fluid Sensor Textile with Enhanced Triboelectric Effect on All-Immersed Dendritic Liquid-Solid Interface.

Enormous interests have been attracted on exploiting interfacial triboelectric effects for sensor and energy applications but immensely limited by the inefficient liquid-solid electrification in terms of immersed applications in fluid. Here, we have presented a flexible self-powered all-in-one fluid sensor textile, for simultaneously monitoring the velocity, acceleration, and chemical composition based on an enhanced liquid-solid triboelectric effect. The textile was woven from flexible dendritic cable electrodes surrounded by arrays of micrometal dendrites, which could be further coated with a layer of polytetrafluoroethylene nanofibers. Even when completely immersed in the fluid, the textile can efficiently output a combined electric signal for parsing the velocity, acceleration, and chemical composition information. Furthermore, a textile of 6 cm2 can charge a commercialized capacitor to 1 V within 80 s by harvesting flow energy on the liquid/solid interface, showing a potential use as the power supply of a signal-processing circuit. It has proposed a promising fluid sensor without extra power cables, for alerting possible leakage or blockage inside chemical and petroleum pipelines.